Kuvatud on postitused sildiga Water. Kuva kõik postitused
Kuvatud on postitused sildiga Water. Kuva kõik postitused

Mine water as a potential source of energy from underground mined areas

Mine water as a potential source of energy from underground mined areas in Estonian oil shale deposit



Paper: Geotechnical Processes and Soil-Water Movement with Transport of Pollutants

Paper: Geotechnical Processes and Soil-Water Movement with Transport of Pollutants in the Estonian Oil Shale Mining Area

Lõputranšee

http://www.minest.ee/water
txt: GEOTECHNICAL PROCESSES AND SOIL-WATER MOVEMENT WITH TRANSPORT OF POLLUTANTS IN THE ESTONIAN OIL SHALE MINING AREA Tallinn Technical University, Department of Mining 82, Kopli Str., 10412 Tallinn, Estonia Abstract One of the most important industries of Northeast Estonia is oil shale mining. Ground movements caused by mining reach the ground surface easily due to shallow location of workings. A new, artificial topography is formed on undermined areas, where the ground surface depressions are alternating with rising grounds. When the Quaternary cover contains loamy sediments, the surface water will accumulate in the depressions. The response of usable lands on undermined areas depends on the degree of changes in the relief and water regime. The accumulation of solid residues by oil shale mines and processing plants has resulted in numerous ash hills, which are polluting the environment. The streams are polluted by phenols, oil products and sulphates. The main source of water supply is groundwater in the oil shale basin. The hydrostratigraphic section is represented by three aquifers. Two (Quaternary and Ordovician) of these aquifers are affected by the human activity. Intensive water consumption has caused a fall in the water level in these aquifers. Due to oil shale production the concentration of Ca2+, Mg2+, SO4 2- and Cl contained in the groundwater from the Ordovician deposits is noticeably higher than in the water with a natural background level. The natural water chemical regime is restored at the cessation of mining. Introduction Estonia is situated on the shore of the Gulf of Finland (Fig. 1) and is characterised by flat topography with only slight differences in elevation. Gulf of Finland Estonia Russia 20 kilometers 0 10 Narva Sirgala Estonia Kohtla - Järve ash dumps Kiviõli ash dumps Kohtla-Järve Sompa Tammiku Ahtme Kukruse Viru Sillamäe Mined out area Claims of oil shale mines Ash dumps Oil Shale outcrop ESTONIA LUXEMBOURG IRELAND DENMARK ANDORRA MONACO LIECHTENSTEIN BOSNIA AND HERZEGOVINA FR. YUGO. REPUB. OF MACEDONIA ARMENIA ICELAND LATVIA MOLDOVA LITHUANIA SLOVENIA PORTUGAL NETHERLANDS FRANCE SPAIN FINLAND NORWAY SWEDEN GREECE ROMANIA UKRAINE SLOVAKIA CZECH REPUBLIC POLAND BELARUS RUSSIA GEORGIA MALTA Fig. 1 Location map of Estonian oil shale deposit. Oil shale reserves are concentrated in North-East Estonia (Fig. 1) and make up about 3,8 billion tons, half of which can be mined according to existing technology, economical and ecological criteria. The annually exploitable layers have an average thickness of 2,6 m and the bedding depth increasing in the southern direction. Oil shale consists of 30-40% organic (kerogen) and 60-70% mineral matter (mainly carbonates and sandy-clayey minerals). The sulphur content averages 1,6 %, the net calorific value varies from 6-10 MJ/kg. Oil shale output increased from 2 million tons in 1940 to 31 million t in 1980, and has since decreased to 12 million tons (Fig. 2). 0 5 10 15 20 25 30 35 1920 1940 1960 1980 2000 2020 Output, Mt per year Output Forecast Fig. 2 Estonian oil shale annual production (mining output) and forecast by Enno Reinsalu (Reinsalu, 1998) The study object was of 290 km2 underground and 130 km2 strip mined area (Valgma, 2002). Oil shale is presently excavated in two surface and two underground mines. For excavation oil shale the mines must be dewatering. The mine water pumped up the oil shale underground and surface mines and discharged into rivers forms on the average 86% (quantitatively 159- 226 millions m3 /yr). In the region of oil shale mining on an average 15 million m3 of water is being pumped out of mines monthly (Fig. 3). Mines drainage causes the depletion of ground- 0 5 10 15 20 25 30 35 40 45 January February March April May June July August September October November December million m3/month 1999 2000 2001 2002 Fig. 3 Water, which pumped out of surface and underground mines monthly water, resulting in drawdown of 20 m in the northern and 70 m in the southern part of mining area. The infiltration of contaminants grows and the main aquifers are chemically polluted over a large area. The formation of the chemical composition of water is influenced by considerable variation of hydraulic conductivity, numerous faults in the strata, karst and, in addition, depressions forming during mining. Evidently each singular case represents a plurality of underlying causes and hence a considerable variety of analytical results depending on the location and season of sampling. Methods During years 1998...2001 geotechnical processes of closed underground oil shale mines and opencasts were investigated. A digital map of Estonian oil shale mining was created for joining data of technological, environmental, and social limitations in the deposit. The main objective was the stability of underground mined area. The stability was studied with help of aerial photographs, mine drawings, maps of quaternary sediments and mathematical modelling of rock failure. Water sampling took place during the spring and summer from 1988 to 1990. This period samples were from tectonic faults and karst fissures in mines, and also from pumped public supply or private boreholes. Springs and rivers were also sampled to obtain a reasonably complete hydrochemical understanding of the hydrogeological cycle in this area. The chemical analysis from more than 20 constituents was carried out on water samples from each of the 31 sampling sites. From Eesti Põlevkivi Ltd. and Estonian Geological Survey were received the official data for the period 1991-2002 and these are following: annual amounts of mine waters, chemical content of water, annual influxes of sulphates with mine waters, data of water regime, the chemical content of ash dumps water. Results The main influences of underground mining on the surface are spontaneous collapses and subsidences. Subsided land is located above hand-mined, advancing-and-retreating mining and longwall mining with double-unit-face areas. The relief of subsided land depends on the quantity of the filling material and filling quality, and on roof structure. Information was collected mainly about random spontaneous collapses of drifts and spontaneous collapses of room-and-pillar mining. Some information is collected about induced caving of longwall mining in Kohtla mine. Considering that longwall mining was stopped in the Estonian deposit in the year 2001, the information about induced caving should be collected and analysed as well. The area of subsidence moulds is in average 55600 m2 ranging from 2500 to 152500 m2 in total. There are 3.1 km2 subsidence areas. Some of the spontaneous collapses mentioned by mining surveyors cannot be recognized on the surface and some seen on the surface have not been reported. In these cases the fieldwork was done with GPS device and caving possibilities considered with the help of digital maps. Cavings have been found in the areas where mines operated within the period of 1963...1989. Surface mining mapping included digitising haulage and mining trenches, loading points, dewatering constructions like ditches, basins and tunnels. Besides, yearly mining ranges were digitised. Created database includes geological characteristics and data of the used technology. Map of yearly mining ranges offers a good overview of the mining period, speed and extent. The present open-cast landscapes can be divided into four classes. The first one is the afforested (mainly with pines) area. The second one is the area with poor vegetation, small trees and bushes, fifty per cent of it being a rocky surface. The third one is a graded area, mainly without vegetation but ready for planting. The fourth area has spoils that are not graded and have no vegetation; their surface angles are reaching the angle of the repose, maximum 45o. One year stripping equals 1-3 trenches. As an example, the former Narva open-cast has been modelled. Digital elevation model (DEM) was created from geological, topological and mining data. There are two principal types of spoils in open cast mined areas. First is formed by beginning mining technology in 1925 to 1950. Oil shale layers were mined by handwork and overburden was stripped by 3 m3 steam excavator in cooperation with spreader. The width of the mining pit was 20 m, forming spoils with maximum slopes 20o. The thickness of the oil shale layer was 2.6 m and the overburden thickness varied from 5 to 12 m. Average stripping factor was 1.9 m3 t-1. Due to this, average height of the ground in the mined out area is from 0 to 2 m below original ground surface, forming deeper and higher peaks. Depending on that, the moisture content of spoil might be higher than that of the soil in the same area before mining. Since spreader and mechanical shovel were used for stripping, the estimated swell factor of the material was 1.3. Maximum size of the material could be 1.4 m due to bucket size and average size was 150 mm. Because of low mobility of the spreader and missing reclamation requirements, the unevenness of the spoil varies between 0.5 and 2 m. The content of organic matter in the spoil, originating from kukersite oil shale, is on average 4%–6%. That material is evenly spaced in the spoils due to stripping method. The second type is mined with newer technology beginning from 1950ties. The area was mainly covered with swampy forests and bogs. Oil shale layers were mined by blasting and overburden was blasted and stripped by 15 m3 and 90 m long boom draglines. The width of the mining pit was 50 m, forming spoils with maximum slopes 3o. The thickness of the oil shale layer was 2.0 m and the overburden thickness varied from 11 to 17 m. Average stripping factor was 4.1 m3 t-1. Due to this, average height of the ground in the mined out area is about 2 to 4 m above the original ground surface. Depending on higher surface than natural and water pumping due to operating open cast, the moisture content and seepage of the spoil might be lower than in the first area. Organic part of the left oil shale layers is mostly in bottom. Dragline and in some cases mechanical shovel were used for stripping of blasted overburden rock, therefore the swell factor of the material was 1.4. Maximum size of the material is 3.1 m due to bucket size and average size was 300 mm. Unevenness of the spoil ranges from 0.5 to 1.5 m on average, but it can be up to 6 m in test sections. The content of organic matter in the structure of spoils, originating from kukersite oil shale, is on average 2% being 4% in bottom and 1% in surface of the spoil. Due to stripping method the material is unevenly spaced in the spoils, the estimated swell factor is up to 1.5 in the bottom. This is another reason for water runoff from the spoils. Because of several mines are being closed during next few years the problems of drowned waste are going to be more actual than before: increase of underground water level, underground water pollution, technogenic water sources and over flooding of reclaimed areas. The chemical analyses of groundwater divide into two principal groups (Fig. 4): - a very large group of CaHCO3 waters; - a large group of Mg(Ca)SO4(HCO3) waters. 0 100 200 300 400 500 600 700 mg/l underlying 7 4 67 17 309 10 10 overlying 10 9 59 30 356 10 9 closed mine (Tammiku, Sompa, Kukruse, Ahtme) 30 7 181 47 385 370 36 working mines (Estonia, Viru) 20 10 156 50 427 620 57 surface mines (Sirgala, Narva) 12 8 174 55 353 530 35 Na K Ca Mg HCO3 SO4 Cl Figure 4. Chemical compositions of groundwater and mining water The influence of groundwater consumption, dewatering of surface and underground mines on the groundwater regime was evident. In the course of oil shale mining at the Estonian oil shale deposit three stages of Ordovician aquifer system have been partially or totally drained. The observation data show that all the aquifers are interconnected and oil shale mining exerts a remarkable influence on all of them. Contamination in this region is mostly due to pollution caused by power and chemical industries. Studies of ash hills demonstrate that the ash may be highly enriched in certain potentially toxic elements, typically semi-volatiles, such as boron, arsenic, antimony etc. The ash dumps water (Table 1) is typically rich in oxides and may have an extremely high (alkaline) pH, which may render some metallic or semi-metallic species highly mobile. Table 1. The composition of the ash dumps water Content, g/m3 Pollutants Interval Maximum Chemical oxygen demand (COD) 4000-8000 18000 Biochemical oxygen demand (BOD) 2500-4000 6400 Phenols 200-580 1400 Volatile phenols 80-110 150 Oil products 30-70 100 Benzo(a)pyrene, g kg-1 0.05-0.15 0.22 Sulphides 100-230 270 Dry matter 3500-6000 7300 Suspended solids 300-600 1300 Total hardness, eqv m-3 30-47 53 pH 11.4-12.2 12.5 There is increasing evidence that portions of the water infiltrating through the soil surface may move rapidly through the aeration zone along preferred flow paths such as macropores and fractures. This rapid, concentrated flow may also have significant implications for the transport of pollutants to the groundwater body. Discharge into the macropores and the concentrated groundwater recharge in the vicinity of the macropores occurred in relation to the development of the groundwater mound. Incorporation of the soil-water movement would bring better prediction of the time, location and magnitude of groundwater pollution due to the transport of pollutants by the infiltrating water. Discussion The basic processes that determine the chemical composition of water in the samples can be classified as follows: - chemical composition of water in the structurally undamaged aquifers; - chemical processes taking place in the sites of tectonic damage and erosion; - infiltration of groundwater (atmospheric precipitations and extracted water) through loading layers; - man-made changes in the environment. As a result of the combined influence of these processes the natural bicarbonate-type water, characteristic of the Ordovician aquifer of the given region, has changed into sulphate- bicarbonate water, having increased from 0,2...0,3 g to 1,0 g/l. Essential role in the formation of the chemical composition of water, especially in shaping local singularities, is played by tectonic damages and karst; in that case the value of the hydraulic conductivity increases. In the regions where tectonic faults are widespread general mineralization may be twice as high as that usually characteristic of water aquifer. Concentrations of Na+ , Ca2+ and Cl are also much higher. Very significant part in the formation of the chemical composition of waters is played by depressions that have sprung up in the course of mining. Their impact is two-hold: infiltration and water exchange increase significantly and with the alteration of aeration conditions a geochemical environment with new physical-chemical properties is formed. Conclusions Natural hydrogeological conditions in Northeast Estonia were simple, but they have been disturbed by the mining industry and consumption of the groundwater. Deeply fractured carbonates, together with effects of mining, have facilitated the rapid spread of aquatic pollution. Mineralised mine water extraction is useless, and the reduction of its mineralization level by technological means or natural filter systems is a problem which needs tackling in the near future. Today this water is guided to natural water bodies. As the content of sulphates in mining waters is high, the concentration of sulphates in the bottom sediments of many water bodies has risen sharply. Due to strong eutrophication there is an oxygen deficiency in some places and the reduction of sulphates to toxic H2S already occurs. The study was supported by EstSF GRANTs G3403 and G4870. Bibliography 1. Reinsalu, E. Is Estonian oil shale beneficial in future? Oil Shale, 15/2, 1998, 97-101. 2. Valgma, I. Estonian oil shale resources calculated by GIS-method. Symposium on Oil Shale., Tallinn, Estonia, 18-21 November 2002

Possibilities of mining under the mire

Paper: Possibilities of oil shale mining under the Selisoo mire of the Estonian oil shale deposit
Raba

txt: See discussions, stats, and author profiles for this publication at: https://www.researchgate.net/publication/236005585 Possibilities of oil shale mining under the Selisoo mire of the Estonia oil shale deposit Article in Environmental Earth Sciences · December 2013 DOI: 10.1007/s12665-013-2396-x CITATIONS 17 READS 98 5 authors, including: Some of the authors of this publication are also working on these related projects: Rikastamine View project Vivika Väizene Tallinn University of Technology 91 PUBLICATIONS 250 CITATIONS SEE PROFILE Juri-Rivaldo Pastarus Tallinn University of Technology 36 PUBLICATIONS 61 CITATIONS SEE PROFILE Ylo also Ülo also in Russian Юло Joann Systr… Tallinn University of Technology 15 PUBLICATIONS 45 CITATIONS SEE PROFILE Ingo Valgma Tallinn University of Technology 404 PUBLICATIONS 1,503 CITATIONS SEE PROFILE All content following this page was uploaded by Ingo Valgma on 11 March 2015. The user has requested enhancement of the downloaded file. All in-text references underlined in blue are added to the original document and are linked to publications on ResearchGate, letting you access and read them immediately. Look Inside Get Access Find out how to access preview­only content Environmental Earth Sciences December 2013, Volume 70, Issue 7, pp 3311­3321 Date: 27 Mar 2013 Possibilities of oil shale mining under the Selisoo mire of the Estonia oil shale deposit Abstract The paper presents results of the study on oil shale mining (Estonia underground mine) possibilities under the Selisoo mire. The Selisoo area is 2,051 ha in extent, and most of the mire is in natural state. Peat layer consists of thick (4.4–6.5 m) oligotrophic peat. Mining under Selisoo will go at depths 65– 70 m under the surface. The mining field of the Estonia mine was planned between Ahtme and Viivikonna fault zones. The lowest hydraulic conductivity of carbonate rocks 0.11 l/day per m2 is found in the Oandu layer and for peat it is 0.35–0.0002 m/day. Therefore, together they form a good aquitard. When the annual rainfall amount is the highest, the difference between horizontal water inflow and runoff is positive with 127,000 m3 . Positive water balance is guaranteed in case of precipitation being at least 540 mm/year. The positive water balance is important for preserving the ecological system of Selisoo mire. For guaranteeing long­term stability of mine pillars, a new calculation method has been elaborated, based on the conventional calculation scheme, where the factor of safety is more than 2.3. Rheological processes are out of question, collapse of the pillars is impossible. Stability of the underground constructions and overburden rocks must be “eternal”. The criteria were elaborated for oil shale mining and will guarantee preservation of mires in natural or close to natural state. Article Metrics Citations 5 Social Shares References (52) 1. Botch MS, Masing VV (1979) Ecosystems of USSR. Nauka, Leningrad. [in Russian] 2. Fetter CW (1994) Applied hydrogeology, 3rd edn. Macmillan College Publishing Company, Inc, New York, Library of Congress Cataloging­in­Publication Data, pp 1– 691 3. Hints L (1997) Aseri Stage Lasnamägi Stage Uhaku Stage Kukruse Stage Haljala Stage. In: Raukas A, Teedumäe A (eds) Geology and mineral resources of Estonia. Estonian Academy Publishers, Tallinn, pp 66–72 4. Hints L, Meidla T (1997) Keila Stage Oandu Stage Rakvere Stage Nabala Stage. In: Teedumäe A, Raukas A (eds) Geology and mineral resources of Estonia. Estonian Academy Publishers, Tallinn, pp 74–81 5. Huang S, Li X, Wang Y (2012) A new model of geo­environmental impact assessment of mining: a multiple­criteria assessment method integrating Fuzzy­AHP with fuzzy synthetic ranking. Environ Earth Sci 66(1):275–284. doi:10.1007/s12665­011­1237­z CrossRef 6. Ivanov KE (1975) Water exchange in peatlands. Gidrometeoizdat, Leningrad, pp 86–91 [in Russian] 7. Joosten H, Clark D (2002) Wise use of mires and peatlands. International Mire Conservation Group, International Peat Society, Saarijärvi, p 303 8. Jõgar P (1983) Ground­water flow models of Pandivere Upland (northeast Estonia). In: Proceedings of academy of sciences of ESSR. Geology 32, 2, 69–78 [In Russian, summary in English] 9. Karu V, Västrik A, Anepaio A, Väizene V, Adamson A, Valgma I (2008) Future of oil shale mining technology in Estonia. Oil Shale 25(2S):125–134 CrossRef 10. Kattai V, Vingisaar P (1980) Structure of the Ahtme tectonic disturbance. In: Proceeding of the academy of sciences ESSR. Geology 29, 2, 55–62 [In Russian, summary in English abstract] 11. Ketcheson SJ, Price JS (2011) The impact of peatland restoration on the site hydrology of an abandoned block­cut bog. Wetlands 31(6):1263–1274. doi:10.1007/s13157­011­ 0241­0 CrossRef 12. Kink H (1997) Karst and springs. In: Teedumäe A, Raukas A (eds) Geology and mineral resources of Estonia. Estonian Academy Publishers, Tallinn, pp 389–390 13. Koitmets K, Reinsalu E, Valgma I (2003) Precision of oil shale energy rating and oil shale resources. Oil Shale 20(1):15–24 14. Loopmann A (1996) Formation, development and perishing of mire massis. Development of mires and formation of bed­pool complex. J Estonian Peat 3(4):18–21 [in Estonian, with English summary] 15. Lu W, Luo Y, Chen M et al (2012) An introduction to Chinese safety regulations for blasting vibration. Environ Earth Sci 67(7):1951–1959. doi:10.1007/s12665­012­1636­9 CrossRef 16. Mining­law and legal regulation acts (1998) Ministry of Environment, Ministry of Economy. Part II, Tallinn, (in Estonian) 17. Nestor H, Soesoo A, Linna A, Hints O, Nõlvak J (2007) Ordovician in Estonia and southern Finland. MTÜ GEOGuide Baltoscandia, Tallinn, pp 1–32 18. Niinemets E, Pensa M, Charman D (2011) Analysis of fossil testate amoebae along the hummock­lawn­hollow gradient in Selisoo Bog, Estonia: local variability and implications for palaeoecological reconstructions in peatlands. Boreas 40:367–378 19. Orru H, Orru M (2006) Sources and distribution of trace elements in Estonian peat. Symposium on peatlands—basin evolution and depository of records on global environmental and climatic changes location: Florence, Italy. Glob Planet Change 53(4):249–258. doi:10.1016/j.gloplacha.2006.03.007 CrossRef 20. Orru M (1975) Report of exploration­investigation works of peat deposits in KohtlaJärve County. Manuscript at depository of manuscript reports of geological survey of Estonia. Geological survey of Estonia, Tallinn (in Estonian, with Russian summary) 21. Orru M (1995) Estonian mires. Geological Survey of Estonia, Tallinn (in Estonian, with English summary) 22. Orru M (2010) Dependence of Estonian Peat deposit properties on landscape types and feeding conditions. PhD thesis, Publication of Tallinn University of Technology, Tallinn, pp 121 23. Orru M, Lelgus M (2003) Peat resources investigation of Soosaare peatland in Viljandi County, the Geological Survey of Estonia, Tallinn, pp 33 24. Orru M, Orru H (2008) Sustainable use of Estonian peat reserves and environmental challenges 15th Meeting of the Association­of­European­Geological­Societies location: Tallinn, Estonia Date: Sep 16–20. Estonian J Earth Sci 57(2):87–93. doi:10.3176/earth.2008.2.04 CrossRef 25. Orru M, Uebner M, Orru H (2011) Chemical properties of peat in three peatlands with balneological potential in Estonia. Estonian J Earth Sci 60(1):43–49. doi:10.3176/earth.2011.1.04 CrossRef 26. Parker I (1993) Mine pillar design in 1993: computers have become the opiate of the mining engineers. Mining engineering, 1993, July and August, 714–717 and 1047–1050 27. Pastarus J­R (2005) Improved underground mining design method for Estonian oil shale deposit. 5th international scientific and practical conference on environment, technology and resources. 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In: Teedumäe A, Raukas A (eds) Geology and mineral resources of Estonia. Estonian Academy Publishers, Tallinn, pp 163–177 34. Puura V, Vaher R (1997) Tectonics. In: Raukas A, Teedumäe A (eds) Geology and mineral resources of Estonia. Estonian Academy Publishers, Tallinn, pp 163–177 35. Reinsalu E (2001) Post technological processes in mined out areas. Estonian Science Foundation, Grant No. 3403, Tallinn (in Estonian) 36. Reinsalu E, Valgma I (2007) Oil shale resources for oil production. Oil Shale 24:9–14 37. Riet K (1974) About transmission capacity of Ordovician carbonate rock in the Estonia oil shale deposit. In: Proceeding of the academy of sciences ESSR. Chemistry. Geology 23, 3, 274–277 38. Regulation to room, pillars and safety zones calculation methods for underground oil shale mining (1997). Tallinn, pp 28 (in Estonian) 39. Sabanov S, Tohver T, Väli E, Nikitin O, Pastarus J­R (2008) Geological aspects of risk management in oil shale mining. Oil Shale 25(2):145–152 CrossRef 40. Scott B, Ranjtih PG, Choi SK et al (2010) Geological and geotechnical aspects of underground coal mining methods within Australia. Environmental Earth Sciences 60(5):1007–1019. doi:10.1007/s12665­009­0239­6 CrossRef 41. Sokman K, Kattai V, Vaher R, Systra YJ (2008) Influence of tectonic dislocations on oil shale mining in the Estonia deposit. Oil Shale 25(2):175–187 CrossRef 42. Systra YJ, Sokman K, Kattai V, Vaher R (2007) Tectonic dislocations of the Estonian kukersite deposit and their influence on oil shale quality and quantity. In: 15th MAEGS meeting 16–20 Sep 2007, Tallinn, Estonia. Abstracts. pp 74–76 43. Taylor JR (1982) An introduction to error analysis. In: Commins ED (ed) The study of uncertainties in physical measurements. University Science Books, California, p 272 44. Tousignant M­E, Pellerin S, Brisson J (2010) The relative impact of human disturbances on the vegetation of a large wetland complex. Wetlands 30(2):333–344. doi:10.1007/s13157­010­0019­9 CrossRef 45. Tutorial for digital mapping for Estonia geology (2008) Land Board (in Estonian) 46. Undusk V (1998) Safety factor of pillars. Oil Shale 15(2):157–164 47. Valgma I (2003) Estonian oil shale resources calculated by GIS method. Oil Shale 20(3):404–411 48. Valgma I (2009) Oil Shale mining­related research in Estonia. Oil Shale 26(4):150–445 CrossRef 49. Valgma I, Kattel T (2005) Low depth mining in Estonian oil shale deposit­Abbau von Ölschiefer in Estland. In: Kolloquium Schacht, Strecke und Tunnel 2005: 14. und 15. April 2005, Freiberg/Sachsen: Kolloquium Schacht, Strecke und Tunnel 2005: 14 und 15. April 2005, Freiberg/Sachsen. Freiberg: TU Bergakademie, 213–223 50. Valgma I, Reinsalu E, Sabanov S, Karu V (2010) Quality control of oil shale production in Estonian mines. Oil Shale 27(3):239–249 CrossRef 51. Väli E, Valgma I, Reinsalu E (2008) Usage of Estonian oil shale. Oil Shale 25(2S):101– 114 CrossRef 52. Wu Q, Liu S (2011) The classification of mine environmental geology problems in China. Environ Earth Sci 64(6):1505–1511. doi:10.1007/s12665­010­0503­9 CrossRef About this Article Continue reading... To view the rest of this content please follow the download PDF link above. Over 8.5 million scientific documents at your fingertips © Springer International Publishing AG, Part of Springer Science+Business Media View publication stats

Mine water and dewatering of mining

Mine water and dewatering of oil shale, limestone and phosphate rock mining in Estonia

Influence of water discharging on water balance and quality in the Toolse river in Ubja oil shale mining region


Paper: Influence of water discharging on water balance and quality in the Toolse river in Ubja oil shale mining region

Oil Shale mining-related research in Estonia

txt: Oil Shale, 2009, Vol. 26, No. 4, pp. 445–450 ISSN 0208-189X doi: 10.3176/oil.2009.4.01 © 2009 Estonian Academy Publishers EDITOR’S PAGE OIL SHALE MINING-RELATED RESEARCH IN ESTONIA Finally the long-announced changes arrived, caused by environmental, geological and technological changes in oil shale mining sector. In addition, the biggest change has occurred with alteration of professionals’ generation. In most of the countries, the institutions dealing with mining are facing difficult questions – to continue or not to continue, and if, then how. Research, development and teaching work are facing a low at the moment. The biggest section in oil shale business in which saving and effectiveness could be achieved is the mining sector. It includes social and environmental restrictions in deposits, losses in pillars and separation of products and waste rock. Losses are closely related to backfilling and waste rock usage. Much smaller sections include production of oil, electricity and chemicals in which most of the research and development is performed today. Efficiency of oil shale usage depends manly on mining technology. 446 Editor’s Page Current urgent topics for investigating, testing and developing of oil shale mining related questions are backfilling, mechanical extracting of shale and digital modelling of mining processes. Estonian oil shale mining industry with its 90 years of history has been a test polygon for equipment manufacturers, geologists and mining engineers from Germany, Soviet Union, Finland and Sweden. These are the reasons why Estonia has recently hosted in average one international mining-related conference per year and is going to host the most important and highest level of the conferences – Annual General Meeting of the Society of Mining Professors “Innovation in Mining” (SOMP AGM 2010, http://mi.ttu.ee/somp2010). Mining research concerning Estonian oil shale deposits Several mining-related factors, such as changes in environment, underground conditions, landscape and property, tend to awoke public resistance. In order to create sustainable mining conditions, research on the natural environment and experiments conducted in mines and mined areas are required. Together with physical experiments, computer modelling is a widespread method in mining engineering. The principal task of modelling is to choose criteria and constraints satisfying all involved parties, as well as ways of presenting. In reaction to this, various restrictions for mining (mainly environmental ones) are created. In most cases, their argumentation is onesided, often subjective. As a result, it is not possible to exploit a large part of deposits due to environmental restrictions, but also due to expiration of evaluation criteria of the supplies of resources. Part of the problems is caused by miners that do not apply environmentally friendly mining technologies. Mining environment is understood as the entity including resources (deposits and groundwater), land (agricultural and housing land), engineering and technology. Research has shown that ground and landscapes changed by mining can afterwards be of better quality than before. If reclaiming is planned skilfully, the soil, landforms, forest, water bodies and agricultural land can be more valuable than before mining. All this is the basis for developing acceptable, environmentally friendly mining. Acceptable mining requires engineering research concerning both natural and technogenic environment, e.g. modelling and pilot projects. As such research is voluminous, computer modelling has become the principal tool in solving problems related to all sorts of developments, technologies and effects. The key issue is defining criteria and restrictions that satisfy all the involved parties. Creating models and estimation criteria requires miningrelated expertise and a database acquired from measurements, experimenting and laboratory testing. Modelling is followed by laboratory and industrial experiments, which require profound know-how. The experiments include e.g. chronometry of technological productivity, geometric and geological measurements, and measurements of rock quality. The parties that compose mining plans, development plans and estimations of environmental effects Editor’s Page 447 have acquired planning and modelling software for various purposes, which causes some problems: the geological database requires skilful treatment; data exist in several geodetic coordinate systems and include partly obsolete stratigraphic terminology. Unfitting coordinate systems disturb the usage of cross-use of spatial data in various geoinformation databases (digital maps, border files, land registers, building registers, databases of technological networks of enterprises, etc.). This creates further problems related to mined areas. Most environmental restrictions, which have to be taken into account in mining and building, are not based on real measurements. Usually the restrictions are two-dimensional and do not take into account the structures of the geological environment. Such vagueness does not support precise engineering calculations or modelling. Basic modelling systems that are designed in developed mining countries are principally meant for deep deposits. However, in Estonia there are blanket deposits, which cause wider environmental effect of mining. Because of that, imported systems have to be adapted. Mining is possible in any circumstances, provided that sustainable mining environment has been created. In other words, with the proper choice of mining technology, the effect of mining has been damped below the level that the nature and man can tolerate. The methodology and criteria for planning, designing, modelling and accepting of sustainable mining environment will provide the basis for mineral raw material that the economy requires, both in the near and far future. The principal direction of developing mining technology is filling the mined area. This provides control over majority of environmental effects. For instance, filling the workings decreases the loss of resources and land subsidence, and at the same time provides usage for stockpiling. Filling the berms of surface mine decreases dewatering; harmless waste can be used for filling open mines and in this manner offer new building land. Local land subsidence related to mining may extend also to technological networks. It is possible to find out deformation parameters by geodetic monitoring. Taking these parameters into account enables to model further the extent and effect of the deformation. Modelling, including digital planning, is aimed at gaining and creating the following: mining indicators needed for making decisions, future scenarios of mining oil shale and building material, support for development planning at state and regional level, technological solutions that take into account all possible environmental effects and social reactions, new output: project solutions, theme maps, inquiries, zoning, evaluations of crises or risks, optimal methodology for gaining, storing and using information, having in mine requirements for various purposes and levels, more effective usage of geological, technological and spatial information, additional functionality of the database. The optimal solution is obtained by modelling. The most general but also dominant criteria are: minimal effect on man and nature, minimal amount of 448 Editor’s Page residual and waste, maximal economic profit, also in other fields not only in the mining industry. The problem includes several criteria, and its solving requires both theoretical and computational solutions. Principal methods are related to introducing sensors, measuring equipment and mining condition experiment, matching structures of various data and modelling based on them. The methods are: mapping the modelling criteria, indicators and processes of the mined areas; experimenting the possibilities of application, compatibility and results of mining software; applying laboratory experiments and fieldwork in modelling; creating models for blanket deposits (methodology in modelling MGIS, i.e. mining geoinformation system, models of new mines, changes in ground conditions, environment (modelling and analysis of groundwater dynamics, effects of dust, noise, etc.), geotechnological models in mined areas); applying seismological methods for developing theory for collapse risk, analysis methods for creating spatial models from geodetic spatial information, studies on material properties for developing theory for criteria for rock breakage, dendrochronologic studies for monitoring changes caused by collapses and changes in the water regime. As a result, conditions for creating mining environment satisfying all involved parties (industry, state, public, decision makers) will be developed, applicable for any deposit of any resource. A system of criteria of evaluating the mining environment will be designed. This research provides for mining science a new level of digital modelling of blanket deposits, basing on long-term experiments and modern digital planning. The research results will be applied in compilation of the state development plan, planning mined areas, as well as in teaching and science. The results are relevant principally for users of land and ground (builders, geologists, hydrogeologists, hydrologists, mining engineers and reclaimers). The results provide better understanding between the public and the miners, and further a basis for well-argumented communication and promotion for economy in the manner that satisfies both parties. In recent years, there has been a world-wide initiative for research, creating the concept of sustainable mining, using relevant indicators and making decisions based on them. MMSD (Mining, Minerals, and Sustainable Development), SDIMI (Sustainable Development Indicators for the Minerals Industry) and other international networks emphasize the need for creation of a concept for regional sustainable mining, relevant for local conditions. At the same time, modelling systems are being built and usage of non-traditional fuels is being started. About three decades ago oil-shale mines of the former USSR including Estonia did not use the progressive mining methods with continuous miner, which are most suitable for the case of high-strength limestone layers in oilshale bed. Therefore, oil shale mining with blasting has been used as a basic mining method in Estonian minefields up to now while continuous miner was tested for roadway driving only. As for cutting, the installed power of Editor’s Page 449 coal shearers and continuous miners has increased enormously since the original work. The actual state of the market has changed, and a wide range of powerful mining equipment from well-known manufacturers like DOSCO, EIMCO, EICKHOFF, etc. is available now. Estonia has 30 years of experience in cutting with longwall shearers which were not capable of cutting hardest limestone layer inside of the seam. Tests with road headers have been carried out in the 1970s. Additionally Wirtgen surface miners have been tested (SM2100 and SM2600) for two years as well as SM2200 and Man Tackraf surface miner, and currently the testing of Wirtgen surface miner SM2500 for high selective mining in an open cast mine is being performed. The main field to be developed in addition to mine backfilling is mechanical extraction of oil shale. Potentially this allows increasing oil yield, decreasing CO2 pollution, decreasing ash amount, decreasing oil shale losses, avoiding vibration caused by blasting, avoiding ground surface subsidence (in the case of longwall mining), increasing drifting and extracting productivity compared with current room and pillar mining, increasing safety of mining operations. The final aim of the research is to use BAT (best available technology) for underground mining in areas with arduous conditions of coal and oil-shale deposits. The main problems to be solved are: selective cutting of oil shale (15 MPa) and hard limestone (up to 100 MPa), roof support at the face, stability of the main roof, roof bolting, pillar parameters, backfilling with rock or residues (ash) from oil production, water stopping and pumping in problematic environment (30 m3 /t expected). Currently room and pillar mining with drill and blast technology is used underground. Supporting is done with bolts. Mining production is in total around 14 Mt/y, including 7 Mt/y underground. Total raw material amount underground is 12 Mt/y. Tests are made for opening new mines, with total production 15 Mt/y. Continuous miners keep playing a major role in the underground industry in over fourteen countries worldwide. Estonia’s oil-shale industry is at the beginning of introducing modern fully mechanized continuous miner systems, which could increase productivity and safety in the underground mines. A longitudinal cutting head-type miner was first introduced in the former Soviet Union by modifying the Hungarian F2 roadheaders and in the 1970s in Estonia by modifying the Russian coal roadheader 4PP-3. Evaluation of breakability was performed by a method developed by A. A. Skotchinsky Institute of Mining Engineering (St Petersburg, Russia). For this purpose over a hundred samples produced by cutting of oil shale and limestone, as well as taken in mines by mechanical cutting of oil shale were analysed. Evaluations were made for using coal-mining equipment for mining oil shale. Comparative evaluations were made by the experimental cutting of oil shale in both directions – along and across the bedding, including also mining-scale experiments with cutting heads rotating round horizontal 450 Editor’s Page (transverse heads) and vertical axes (longitudinal heads). In both cases the efficiency was estimated by power requirement for cutting. The feasibility was shown by breaking oil shale in direction of cutting across the bedding by using cutting drums on horizontal axis of rotation. The research also evidenced that the existing coal shearers proved low endurance for mining oil shale. Therefore, there arose the problem of developing special types of shearers for mining oil shale or modifying the existing coal shearers. It was further stated that the better pick penetration of the longitudinal machines allows excavation of harder strata at higher rates with lower pick consumption for an equivalent-sized transverse machine. It was reported that with the longitudinal cutting heads the dust forming per unit of time decreases due to smaller peripheral speed. The change in the magnitude of the resultant boom force reaction during a transition from arcing to lifting is relatively high for the transverse heads, depending on cutting head design. Specific energy for cutting across the bedding with longitudinal heads is 1.3–1.35 times lower which practically corresponds to the change of the factor of stratification. These are the questions waiting for answers in the near future for effective oil shale extraction in Estonia and in similar mining conditions. In spite of current economic problems, still everything begins with mining. Ingo VALGMA Head of Department of Mining of Tallinn University of Technology, Head of Estonian Mining Society, President of the Society of Mining Professors / Societät der Bergbaukunde

Developing computational groundwater monitoring and management system

Paper: Developing computational groundwater monitoring and management system for Estonian oil shale deposit

Paper: The impact of infiltration dam on the ground water regime

Paper: The impact of infiltration dam on the ground water regime in the Kurtna Landscape Reserve area



txt: Oil Shale, 2006, Vol. 23, No. 1 ISSN 0208-189X pp. 3–14 © 2006 Estonian Academy Publishers THE IMPACT OF INFILTRATION DAM ON THE GROUNDWATER REGIME IN THE KURTNA LANDSCAPE RESERVE AREA Mining Department of Tallinn University of Technology Ehitajate tee 5, 19086 Tallinn, Estonia The area of Kurtna Landscape Reserve is situated between oil shale mines. This area is an important part of the Estonia deposit, and the located mining conditions there are good. Narva surface mine pumps groundwater from the area of Kurtna Lakes. It is able to minimize the influence of surface mining. Testing of mining technology and hydrogeological modelling show that mine front may be closed for stopping water flow instead of leaving an open trench by the border of the area of the lakes. According to modeling, hydraulic conductivity of the dam must remain 0.1 m/d to avoid sinking of water level in the lakes, and filtration basins must be supplied with water in an amount of 7000 m3 /d as yearly average. As the result, the landscape will be reclaimed, overall look and shape will be smoothed. Abandoned fields of peat milling will be reclaimed, and their fires will be avoided. Introduction The influence of the power and mining industry on Kurtna Lakes located in the centre of the oil shale mining area in North-East Estonia has been a discussion object for the last fifteen years. Oil shale mines surround the area of Kurtna Lakes. There are 40 lakes in a 30-km2 area above a 70-m deep buried valley [1]. Two mines – Estonia and Narva – exert the greatest influence on this. Both mines pump out water from the area and lead it back to the lakes or rivers in the same area. The question is how much the mining influences protected lakes and species. Besides Narva surface mine neighbouring the lakes has claimed the permission to pump groundwater from the lake area (see Fig. 1). Surface mining was stopped at a distance of 2 km from the protected area since the problem had not been solved, thus the mining company asked independent research groups to perform corresponding analyses and to test the mining technology used in this area. * Corresponding author: e-mail ingoval@cc.ttu.ee 4 I. Valgma, H. Torn, K. Erg Fig. 1. Location of the Kurtna Landscape Reserve, mining section and infiltration dam There are two main reasons for mining oil shale in the area. The first reason is oil shale resource. Local reserves represent an important part of the Estonia Oil Shale Deposit [2]. Energy rating of oil shale is one of the best among the potential mining areas reaching 44 GJ/m2 , and depth is relatively low (10 to 15 m) compared to 22 m in the rest part of the surface mining area [3, 4]. This resource is of great economical importance because when mined, total costs of mining will remain stable. On the other hand, pressure on mining oil shale in unsuitable areas will become actual in the future [5]. From these aspects, the application for mining permit is reasoned. Since Estonian main oil shale-fired power plant has been renovated, and new boilers require oil shale of a more stable quality than the former ones, the need for oil shale mining remains actual for at least 25 years, which corresponds to the resource in current minefields [6]. New power units operate applying a new, fluidised-bed technology that guarantees less impact on the environment. Total resources of oil shale in the Estonia deposit guarantee operating of power plants for 60 years [2, 5]. Due to low oil shale quality in the most part of the deposit and additional environmental restrictions, the quantity of mineable oil shale is not as great as it seems. Compared to 50% total loss of oil shale resource in the case of underground room-and-pillar mining, the loss in open cast mines reaches 30% [7]. The losses are due to differences in official and actual resources and oil The Impact of Infiltration Dam on the Groundwater Regime in the Kurtna Landscape Reserve Area 5 shale remaining in supporting, protective and barrier pillars. As for the usage of resources, surface mines are more valuable [8]. The main problems concerning mining fields are related to mining conditions and environmental restrictions. Surface mining is reaching depth limit, while underground mining is confronted by low quality of oil shale, bad roof conditions and environmental restrictions [4, 9]. For these reasons continuation of mining in the section neighbouring the area of Kurtna Landscape Reserve is advisable. Mining in the test section should be performed under continuous monitoring for calibrating dynamic modelling with groundwater software. Influence of oil shale mining on the area of Kurtna Landscape Reserve The influence of mining on the lakes has been investigated from the hydrogeological aspect, recommending the usage of infiltration basins and regulation of water flow [10–14]. Water chemistry has been investigated proceeding from the effect of oil shale mining on sulphate content of water [15]. The influence on the landscape and plants has been studied by analysing plant species and mining waste [16–19]. The set of water wells and lakes in the water monitoring program has been set to analyse changes in ecological situation. Unfortunately, it has not given a clear answer to the question about the influence of mining on the groundwater flow in the area. The reason for that has probably been complexity of situations and lack of an interested party who would evaluate all the aspects concerning this region. The closest lakes (Kastjärv, Aknajärv, Jaala, Kihljärv, Nootjärv, Valgejärv and Virtsiku) are located in a distance 1.5 to 3 km from the front of Narva surface mine. Data of observation wells show that the level has not been remarkably changed due to surface mining operation during the last five years. All these lakes are located in the area of boggy, glaciolacustrine and -fluvial deposits. Drawdown of groundwater has been formed due to an intensive consumption of groundwater at the water intake in the central part of the Vasavere buried valley. Quaternary aquifer is an unconfined waterbearing stratum. The values of porosity and permeability of Quaternary aquifer depend to a large extent upon the degree of sand cementation. Consequently, these values are generally expected to be much higher for the central part of the valley than for the slopes. A study of the samples shows that porosity values exceeding 33% are common for the central part, whereas those less than 20% are usual for the southern part of the valley. Similarly, intergranular permeabilities average 2500–2700 m3 d–1m–2 in the central part and drop to 10–50 m3 d–1m–2 at the border of the valley [20]. Seasonal factors, changing flow and various forms of recharge may all produce fluctuations in the water level of about 1 m. 6 I. Valgma, H. Torn, K. Erg 32 33 34 35 36 37 38 39 40 1999 2000 2001 2002 2003 2004 Water level, m Fig. 2. Sinking of water level shows sand inflow to the trench and quick normalisation of the state after closing the flow. Water wells B 6-1 ja B 6-2 are located between Lake Kastjärv and the dam Fig. 3. Technogenic valley formed after sand flow into the trench in March 1999 Water table of L. Valgejärv lowered 2 m in 1984, caused by water usage for stopping peat fires. For the year 1996, water level was normalised again. Only one remarkable event happened in 1999 when sand basement of the peat field flew into mining trench (see Fig. 2, 3). This happened because the spoil was piled on ice, and when ice melted sand spoil became unstable. The water-table diagram shows that original water level was restored quickly after closing sand inflow. The Impact of Infiltration Dam on the Groundwater Regime in the Kurtna Landscape Reserve Area 7 Mining technology The influence of Narva surface mine at the east side of the lakes’ area could be minimised. First, the mine front can be closed for stopping water flow instead of leaving an open trench in the border the area of lakes. Second, the overburden material that is used for closing the trench can be piled in such a way that it has lower permeability than soil in the nature. Besides, a part of that area is covered with abandoned fields of peat milling. Thickness of the residual peat layer reaches up to 3 m being a good material for decreasing permeability of the final dam material. For testing these assumptions, a test section was planned and designed by Mining Department of Tallinn University of Technology in 1997. The purpose was to test whether the filtration dam will decrease the sinking of water level in the area. Test mining in this section started in 1998. The idea originated from dam-piling experiences in the same mine where a dam has been piled with careful dumping and mixing of overburden material (see Fig. 4). This resulted in accumulation of water behind the dam, a water body now called Lake Vesiloo named after the designer of the dam. Water level in the upper lake has remained stable for 45 years, which proves permeability of piled overburden material consisting of limestone, clayey sand and peat. For evaluating the influence of mining on a larger area, a modflowgroundwater model was set up by independent company AS Maves in cooperation with Mining Department of Tallinn University of Technology [19]. The model is supported by continuous monitoring of water wells and mine-dewatering data. For closing the existing open trench, placement of mine front and stripping technology were changed. The direction of mine front had to be changed by 45 or 90 degrees (see Fig. 5). This could enable building of an infiltration barrier between the lakes and the mine at the end of the trench where only a 30-m-wide pit would be temporarily opened for water infiltration. 36.1m 30.3m Spoil 5.8m Bank Mine bottom Infiltration dam Vesiloo lake Fig. 4. Cross-section of infiltration dam in the mined-out area of Viivikonna section. Water level in Lake Vesiloo has remained 6 m higher from water level in lower lake for 45 years 8 I. Valgma, H. Torn, K. Erg Fig. 5. Layout of water inflow to the mine applying old technology (above), new technology (below) Dragline ES-10/70 is used for piling the dam. Ordinary selective piling of the overburden will be finished at 50 m from the border. Beginning from this point, the material will be disposed homogeneously. Different materials are dumped on top of each other. This should guarantee low permeability of the dam. Important is that the material be dumped from the maximum height of dumping position of the dragline and onto different locations. The width of the dam should be at least 25 m, and the high wall should be covered with a mixture of clayey material and peat. Stripping productivity in the section will be decreased by several factors. Dragline’s cycle time increases because of hauling of the bucket to the maximum height of the dump, repositioning of the boom in every cycle, and careful monitoring of homogenisation of the spoil. Besides, technology of seam extraction in the dam area is affected by many factors. Oil shale interlayer C/D has to be hauled away from the location of the dam because of its high swelling value (up to 200%). Hydraulic conductivity The Impact of Infiltration Dam on the Groundwater Regime in the Kurtna Landscape Reserve Area 9 of this loose material could reach 1000 m/d. Alternatively, the seam has to be extracted non-selectively, leaving a 30-cm limestone layer in the output material. The overall productivity will decrease because the trench is short – 700 m, the optimum length being 1.5 km [21]. This concerns organising stripping, haulage and dam operations in a short section. Optimum length of the section was achieved by positioning the trench at 45 degrees instead of planned 90° in relation to the original North-South direction. (see Fig. 5) The groundwater model was made on several assumptions. Groundwater discharge from the mine should be within certain limits to keep the decrease in the water level of the lakes below the agreed limits. According to the model, hydraulic conductivity of the dam material should not exceed 0.1 m/d. Besides, infiltration basins which are located between the mine front and the lakes should be fed with water in an amount of 7000 m3 /d for complementing soil water of the surroundings and keeping water level in the area stable. Dam material consists of silty fine-grained sand whose modulus of hydraulic conductivity k = 0.1–0.8 m/d depending on density and compaction index of the material, and the content of clay particles. Provided that the test section was piled according to the design, the modulus of hydraulic conductivity of the material in this section could be in limits k = 0.1–0.2 m/d. In addition, the overburden contains moraine (k = 0.01–0.05 m/d), fine-grained sand (k = 0.5–2 m/d) and loose broken limestone (k = 100 m/d). Spoil material dumped conventionally is characterised by k = 0.5–50 m/d. It is assumed, basing on the experience gained from the test section, that fine material will fill spaces in coarse material decreasing permeability of the bank dam. The given solution will not work with drains that could form in the case of piling C/D layer, or with open dewatering tunnels under oil shale bed. The influence of mining on water level and quality of lake water near the test section is unnoticeable that proves the suitability of the technology. However, the conditions will become more complicated in southern direction (see Fig. 6). There are peat, sand and moraine layers in the cross section of the Quaternary sediments and Ordovician limestone in hard overburden, causing high permeability of the spoil. An increase in the thickness of limestone seam in southern direction causes most of the dumping problems in dam building. Additional amounts of sand have to be scraped from aside, probably rehandling the overburden, and, in addition, compactors should be used for achieving proper modules of hydraulic conductivity. Dam piling was modelled applying the geometric model that is used for determining the ultimate pit depth for draglines [9]. The model yields figures about suitability of draglines, need for rehandling and additional scraping, and also differences in the final height of the ground (see Figures 7 and 8). The test section has shown that it is difficult both organisationally and technologically to establish all these parameters. For evaluating the effectiveness of the dam in the southern part, several tests on density, compression and permeability of the spoil material have to be performed and compared with data obtained using the hydrogeological model. 10 12 17 22 27 32 37 42 47 Height, m Soft overburden 13.9 15.5 13.6 10.8 10.9 Hard overburden 5.1 4.2 8.0 9.9 12.1 Oil shale seam 2.8 2.8 2.8 2.8 2.8 Bottom layer 23.2 22.3 19.2 17.5 13.6 1-North 2 3 4 5- South Fig. 6. Thickness of limestone overburden increases in southern direction causing dumping difficulties for draglines and higher hydraulic conductivity of overburden material Fig. 7. Pit at the end of the trench before 1997. Limestone pile on the bottom of the trench forms under spoil drainage channels If the technology of dumped spoil fails, the compactors on the spoil and a geomembran barrier on the bank wall made using contour blasting, or a clay barrier must be applied. The Impact of Infiltration Dam on the Groundwater Regime in the Kurtna Landscape Reserve Area 11 0 10 20 30 40 -100 -80 -60 -40 -20 0 20 40 60 Dragline center Spoil Bank Length, m Fig. 8. Pit layout and modelling of surface height using geometrical model Different materials and constructions are widely used to reduce hydraulic permeability at exploitation of mines, quarries and waste depositories. Depending on purposes, the barriers, dams, sheet piles or cut-off walls of different permeability could be constructed. In Estonia, hydraulic barriers are designed and constructed around Sillamäe Radioactive Waste Depository (bentonite slurry cut-off wall) and Tallinn old municipal landfill (vinyl sheet-pile wall). Watertight clay barriers are widely used in construction of new landfills. Vertical slurry cut-off walls Slurry cut-off walls are vertical walls constructed by excavating a trench and simultaneously filling the trench with a bentonite slurry. The bentonite slurry forms a thin (typically ≤3 mm) filter cake of low hydraulic conductivity (

Paper: Technogenic water in closed mines

Paper: Technogenic water in closed mines Raba Oil Shale, 2006, Vol. 23, No. 1 ISSN 0208-189X pp. 15–28 © 2006 Estonian Academy Publishers The present paper is based on the results of the research conducted in 2004 by the Department of Mining of the Tallinn University of Technology and Estonian Oil Shale Company. The state of the technogenic water body that has formed in the central part of the oil shale deposit is analysed: the water level in the area of the stopped and closed mines, water amount and move- ment direction, water quality and its changes. The state of the water is assessed and predicted using modelling of the water tables, statistical analysis of the water quality parameters and the pilot model for describing the migration of water. The results show that the technogenic water body studied is in a relatively stable state, and the quality of the groundwater in that area is fast improving approaching the drinking water standards. Introduction The Estonia oil shale deposit comprises about ten closed and stopped deep mines that are fully or partly filled with water (Table 1). Eight mines in the central part of the deposit: Ahtme, Kohtla, Kukruse, Käva, Sompa, Tammiku and mines Nos. 2 and 4 form one water body. After Ahtme mine was filled with water in December 2004 (Fig. 1), the water body turned relatively stable. Ubja mine and joint Kiviõli and Küttejõu mine are located in the western part of the deposit, farther away from the other mines. In addi- tion to oil shale mines, Sillamäe uranium mine (1949–1952) [1], and Ülgase (1922–1938) and Maardu phosphorite mines (1942–1965) have been closed in Estonia. The water regime in these mines has not been studied yet and is not discussed in the present paper. * Table 1. Closed and flooded underground oil shale mines Mine Closed – (pumps were stopped) Mined area, km2 * Water table a.s.l., m Outflow regulating the water table Approximate water volume, 106 m3 Central part of the deposit: Kukruse 1967 13 51–54 Mostly into Käva and Jõhvi mines 3.5–6** Käva and Käva-2 1973 18 51–52 From an old adit into Vahtsepa ditch 9–11** Mine No. 2 (Jõhvi mine) 1974 13 51–56 Mostly into Tammiku mine, during flood to Jõhvi city 10–11** Mine No. 4 1975 13 41–42 Mostly into neigh bouring mines 3–8** Tammiku December 1999 40 44–48 Into the Kose River and Viru mine 34 Sompa February 2000 27 40–45 Into neighbouring mines 23 Kohtla June 2001 17 39–42 Into Aidu opencast 13 Ahtme December 2001 – December 2002 35 ≈ 47 From drill holes and springs into Sanniku brook 36 Separate mines in the western part of the deposit Kiviõli & Küttejõu 1989 29 41 ± 0.5 From a ditch into the Purtse River Up to 29 Ubja 1960 2 ≈ 55 From an adit into the Toolse River Not determined Total ≈ 170 * [5] ** Depending on the water level [6] As a rule, the mine workings and groundwater cone of depression formed during mining fill with water after the cease of mine pumping. The degree of filling depends on the mining depth and the height of outflow. The tunnels of Ahtme, Sompa and Tammiku mines are completely, those of mines Nos. 2 and 4 almost completely water-filled. The rest of the mines (Kiviõli, Kukruse and Käva) contain areas with dry floor. The museum founded in Kohtla mine is dry because of to the draining effect of Aidu opencast and the water barriers surrounding the exposition area. The water level changes depending Technogenic Water in Closed Oil Shale Mines 17 10 15 20 25 30 35 40 45 50 2002 2003 2004 2005 Water level, m Tarakuse well Pagari well Fig. 1. Increase in the water table in closed Ahtme mine on the amount of precipitation and water exchange with neighbouring mines. The rate and amplitude of the changes differ from mine to mine. Several problems have arisen from the flooding of the closed mines. First, the technogenic water body started to affect the amount of the water pumped out of the working mines and its seasonal variation [2]. Clearly, the water of the closed mines will influence also the new mines, planned to be constructed in the Ojamaa and Uus-Kiviõli mine fields. Second, the environ- ment is affected by the water that in several places has risen to the pre- mining level (of the year 1945) and by the new springs formed. Several projects have been undertaken to fight the flooding, and it has turned out that no sufficient source data for mine planning are available. Third, the water of the closed mines is an easily accessible water resource, thus it is important to know and predict its quality [3]. Prediction of the mine water quality is essential also because of the fact that groundwater elevation in the mine field has started to affect the water supply of the region – the water richer in sulphates runs into the outdated and leaky common wells. It has also been prognosticated that if the groundwater table rises higher than 45–47 m, the water in the Ahtme mine field will affect the water level and quality of the Vasavere intake [4]. Fourth, the land above old mines has subsided and the rocks are fractured, therefore the technogenic groundwater is weakly protected and the contribution of precipitation to groundwater formation is very high. Water level The present study is based on the water level measurement data (incl. archive data) provided by the Estonian Oil Shale Company, Geological Fig. 2. Map of the technogenic water body Technogenic Water in Closed Oil Shale Mines 19 Survey of Estonia and Municipality of the town of Jõhvi. The water levels of the Keila–Kukruse, Lasnamäe–Kunda and Nabala–Rakvere aquifers, closed mines and main outlets were measured on an average period of 20 years. New data were obtained in the years 2003 and 2004. Field works and monitoring started in the spring of 2004 and are still going on. An essential part of the research was the modelling of the level of the Keila–Kukruse aquifer in the stationary regime. The modelling area included the central part of the deposit – underground mines and Aidu opencast. Data from about 50 observation wells were used. The water level of working mines was described at the level of the oil shale bed floor. Closed mines were treated as independent water sub-bodies, where the water level is constant at a certain moment of time (Table 1). The MapInfo Professional software was used, combined with the modelling package Vertical Mapper. The comparison and calibration of the intermediate results obtained and discussions held showed that the best interpolation method was triangulation with smoothing, because in that case interpolation takes place only between data points or observation wells, without modelling the situation outside the study area. During the first stage of the research the state of the water body in August 2004 was assessed. According to the measurements and calculations performed, precipitation accounts for up to 70% of the water pumped out of mines [2]. The autumn–winter season of 2004 was rich in precipitation, with little snow and relatively warm. Therefore it could be expected that Ahtme mine would fill with water sooner than predicted [4]. To check that hypothesis, the model was calibrated at the second stage of the research in December 2004. The contour map of the modelled water table is shown in Fig. 2. By continuous improvement of the existing and addition of new data more than ten two- and three-dimensional map versions were completed. The model enabled us to assess the water levels in different mines and their border areas and to make assumptions and predictions about the water move- ment directions. Water quality In the years 2000–2004 the department of environmental services of the Estonian Oil Shale Company had the waters of all closed mines analysed. The samples were taken at six sites in four mines in different seasons. Analyses were made at the central laboratory of the Estonian Oil Shale Company (3 analyses), in Tartu Environmental Research Ltd. (2 analyses) and in the Geological Survey of Estonia (12 analyses). Up to 16 quality parameters were determined. The results of the analyses are presented in Table 2. The quality parameters are arranged in Table 2 in the decreasing order of the variation in measurement results. At first glance only the average contents of iron, sulphates and phenols obtained for the observation period do not meet the drinking water standards. This cannot be a final conclusion. The average Table 2. Water quality parameters in closed Ahtme, Kohtla, Sompa and Tammiku mines Quality parameter Unit Number of measurement results Numerical data for the entire period (2000–2004) Leachates Total Certain numerical values Arithmetical mean Standard deviation Variation coefficient Max. levels permitted in drinking water Total Fe mg/l 14 10* 0.69 1.16 1.67 <0.2 NO3 - mg/l 15 11* 11.7 18.55 1.58 <50 NO2 - mg/l 12 7* 0.015 0.0166 1.10 <0.5 SO4 2- mg/l 15 15 342.4 240.2 0.70 <250 Dry residue mg/l 14 14 845.5 569.6 0.67 – Mg2+ mg/l 15 15 51.6 32.58 0.63 – K+ mg/l 13 13 12.9 8.11 0.63 – Ca2+ mg/l 15 15 174.5 107.6 0.62 – Na+ mg/l 14 14 10.4 6.33 0.61 <200 Cl mg/l 15 15 16.4 9.74 0.59 <250 Total hardness mge/l 13 13 13.72 7.04 0.51 – Oil products mg/l 15 4* 0.15 0.073 0.49 <0.05 Conductivity μS/cm 14 14 1095 477.6 0.44 <2500 NH4 + mg/l 12 2* 0.017 0.0064 0.39 <0.5 Total phenols mg/l 15 4** 0.0017 0.00049 0.28 <0.0005 pH 15 15 7.1 0.33 0.05 6.5–9.5 * due to the lack of a certain numerical value the result was smaller than the preciseness of the laboratory tests, but not exceeding the limits permitted in drinking water ** due to the lack of a certain numerical value the result was smaller than the preciseness of the laboratory tests, in two cases not exceeding the limits permitted in drinking water; rest of the samples gave no unique result Notes: Quality parameters are ordered according to the variation coefficient. The shaded lines contain the measurement results the average of which does not meet the Estonian drinking water standard. The content of benzo(a)pyrene was measured in 11 samples. The results are not included in the table because no certain numerical values were obtained. In all samples the benzo(a) pyrene content was lower than the permitted maximum value. and standard deviations given in the table have been calculated for all closed mines and for the entire observation period, thus they characterize only the data set and not the quality of water or a particular mine. Variation in the measurement results is caused by influential as well as random factors. Influential factors are the sampling site (mine) and the time span that has passed since the closure of the mine. Let us treat this assumption as a working hypothesis. A random factor is the season when sampling was performed. For example, in the years 2000 and 2001 samples were taken in summer, in 2002– 2004 in autumn. Surely the water quality parameters depend also on the Technogenic Water in Closed Oil Shale Mines 21 location of the sampling site in the mine field. Some part of variations result from the methodology of sampling and laboratory tests. The reliability of iron content analyses carried out in different laboratories could be questioned. The phenol content of mine water, measured repeatedly during mining, has been 0.003 ± 0.001 mg/l, except for Kiviõli mine, which has been strongly affected by chemical industry. Here the phenol content of mine water was 0.38 mg/l [7]. For preliminary checking of the working hypothesis we conducted a two- factor (place and time) variation analysis of the sulphate and iron contents of Tammiku and Sompa mine waters. The results of sulphate analysis are given in Table 3. We can see that the hypothesis of the influence of place and time on the sulphate content of water is relatively strong (probability of a counter- hypothesis 18.0 and 18.8% respectively). The residual standard deviation (187 mg/l), however, is too large for making definite conclusions. Obviously the result is influenced by taking samples in different seasons. An analogous result was obtained by the variation analysis of the iron content, whereas the impact of time turned out to be small. Possibly this could result from the treatment of samples in different laboratories. In spite of great uncertainty of measurement, the sulphate and iron contents decrease with time. This trend is depicted by graphs in Fig. 3. As could be expected, the purification of water is best described by the exponential function. The constants in the formulae (801 and 0.77 mg/l, respectively) characterize the average concentrations at the initial moment of the dilution process (at the closure of mines) and the time factors (–0.386 and –0.507, respectively) show the rate of water purification. The half-life of the concentration calculated on the basis of time factors, i.e. the time period during which the content of a component decrease twice, is about 1.8 years for sulphates and 1.4 years for iron. From the half-life and graphs we may presume that in about five years after the closure of a mine the content of sulphates and iron decreases below the maximum permitted level in drinking water. The highest permitted content of iron in first-class drinking water is 0.2 m/l and that of sulphates 250 m/l. The data on all mines are included in the graphs of Fig. 3. The measure- ments revealed varying initial concentrations of sulphates for different mines. The highest concentration was recorded in the first sample from Ahtme mine, the lowest in Kohtla mine. Actually, this is not the initial level, since the first samples were taken 4–11 months after the pumps had been stopped. Approximating the results obtained from the samples of each mine separately, we get theoretical dilution of the initial concentration level at the zero moment, about 2200 mg/l for Ahtme and 300 mg/l for Sompa. These values refer to a relation between the depth of the mine and the initial concentration of sulphates. The hydrogeological background of this pheno- menon is discussed by Erg [3]. Table 3. Results of the variation analysis of the content of sulphates Source of Variation df MS F P-value Mines (Tammiku, Sompa) 1 91681 2.63 0.180 Years (2002–2004) 4 92788 2.66 0.183 Error 4 34924 Residual Standard Deviation 187 mg/l Total 9 SO4 2- = 801 e-0.386 t, mg/l R2 = 0.46 10 100 1000 10000 01234567 t - closed, years SO42- - sulphate content, mg/l 250 mg/l Fe = 0.77 e -0.509 t , mg/l R2 = 0.39 0.01 0.1 1 10 01234567 t - closed, years Fe content, mg/l 0.2 mg/l Fig. 3. Decrease in the content of SO4 2- and Fe in closed mines. 250 mg/l and 0.2 mg/l – maximum permitted levels in drinking water. The water quality parameters for which we had at least 14 reliable measurement results (pH, electric conductivity, total hardness, Cl- , dry Technogenic Water in Closed Oil Shale Mines 23 residue, Na+ , Ca2+, Mg2+, K+ and SO4 2- ) were subjected to correlation analysis. From the analysis we could conclude the following: • The content of sulphates can be considered a good indicator of mine water quality, because it correlates well with most of the other water quality parameters, except for K+ . • Electric conductivity can be successfully used for rapid assessment of water quality, because it correlates well with sulphates as well as with other main parameters (except for K+ ). • pH is not informative enough, because it does not correlate with any other water quality parameter. Pilot model of water exchange Continuous water exchange is going on between the closed mines. The water penetrating into mines is derived mostly from precipitation, less from groundwater. The part of the water not flowing out of the mine (Table 1) infiltrates into the neighbouring mines or feeds aquifers. The water pumped out of the working mines is formed of precipitation, groundwater and the water coming from closed mines. Intensity of water exchange depends on the length (L, km) and thickness (l, m) of the barrier left between the mines, difference between the water levels of neighbouring mines (dh, m) and permeability of the barrier and overburden (km, m2 /d). The longer and thinner is the barrier, the greater is the water level difference in neighbouring water bodies, and the higher is the permeability of rocks in the areas separating the mines, the more intensive is the exchange of water. The water levels of the closed mines are precisely known. The measure- ments of barriers can be obtained from the plan of mining works, but the length and thickness of the barriers are highly variable. Little data are available on the permeability of pillars and bedrock. As seen in Table 4, the permeability of the Keila–Kukruse aquifer differs up to 10 times within the limits of the deposit. Water permeability is largely affected by the geological disturbance of the Earth crust (mostly karst zones), which makes the aquifer highly aniso- tropic [8, 9]. In the Estonia mine field twofold difference in the permeability in the northeastern and southeastern directions has been recorded. According to the data by Domanova, anisotropy is especially great in the area of tectonic dislocations, where permeability in various directions may differ several times. Water exchange between the mines is inhibited by extensive karst zones running along the mine field boundaries between Sompa and Viru, and Ahtme and Tammiku mines. At the same time, karst zones running transversely to the mine boundary increase the water exchange between Sompa and Kohtla mines. Additionally, the water exchange is affected by the properties of the mined area, which depend on the roof handling methods used. In the area Table 4. Permeability of the Keila–Kukruse groundwater aquifer in the mining district Filtration module Publication District Permeability, m2 /d Estimated difference in water tables, m m/h m/d Kohtla – Aidu, northern part 1200 5 10 240 Kohtla – Aidu, central part 780 10 3.25 78 [8] Kohtla 6–60 Viru 10–40 [7] Aidu, generalized 393 10 1.6 39 Ahtme, generalized 335 10 1.4 34 [4] Tammiku 4–20 Ahtme 1–15 [7] Ahtme – Estonia 90 10 0.38 9 [4] No. 2 – Tammiku 0.24 6 [10] mined using roof caving the water-bearing horizon is thicker and of higher permeability than in the area of room-and-pillar mining. Because of high uncertainty the calculation of the water amounts moving between the closed mines is complicated, not only due to the variability in L, l, k, but also due to the lack of the relation uniquely describing all the situations. Therefore the present study makes use of the balance method, which unites the amounts of the water pumped out of the working mines, and of precipitation and groundwater infiltrating into the mine. The relation between these amounts is expressed by the approximate formula qij = 365.25 × Lij × kij × (dhij/2) / (1000 × lij), where qij – the amount of the water migrating from one mine (i) to the other (j), million m3 /y, Lij – length of the barrier between these mines, km, lij – average thickness of the barrier, m, dhji – difference between the water levels of two closed mines at the moment of modelling, m, kij – factor characterizing the permeability of the area between the mines (barriers and overlying rock), which, with some reservation, can be considered as generalized permeability, m2 /d. As model input we use the measurements of the barriers between the mines, volume of the water pumped out of the working mines (especially changes in it due to the closure of neighbouring mines), amount of precipita- tion and its relation to mine pumping [2]. The variable parameter of the Technogenic Water in Closed Oil Shale Mines 25 model is generalized permeability, which is used to balance the model. Permeability was fitted into the model taking into consideration the informa- tion available (Table 4), location of mines with respect to tectonic fault zones and the orientation of the karst zones lying between the mines. The balanced model can be used for calculating the migrating water amounts by fluctuations in water level, for example during floods and heavy rains, but also for planning water level regulations. The model output is the matrix of water exchange (Table 5), where • “North” denotes the northern closed mines No. 2, Kukruse, and Käva and its satellite mines • “West” denotes the western closed mines Kohtla, Sompa and No. 4 • “Vasavere” is the area east of Ahtme and Estonia mines • The water amounts in the matrix of water exchange are given in million m3 /y, whereas (+) shows the amounts infiltrating into the mine (i) from the mine (j) and (–) shows the amounts migrating from the mine (i) to the other mine. Explanations to the matrix of water exchange are given in Table 6. Water movement inside the water body and the amounts of mine pumping are shown in Fig. 1. The values presented characterize the state of the water body in the year 2004, but as we have to do with a pilot model, these are all approximate. Table 5. Matrix of water exchange, year 2004, 106 m3 /y ↓Elements of the water body → Aidu Estonia Viru Ahtme Tammiku North West Vasavere Jõhvi city Sum Working mines: Aidu 0.00 0.00 0.00 0.00 0.00 0.00 14.46 0.00 0.00 14.46 Estonia 0.00 0.00 1.64 6.48 0.00 0.00 0.00 0.48 0.00 8.60 0.00 0.00 –1.64 0.00 0.18 7.23 0.00 3.07 0.00 0.00 8.83 Technogenic water body; closed mines (sub-bodies): Ahtme 0.00 –6.48 –0.18 0.00 0.07 0.00 0.00 –1.07 0.00 –7.65 Tammiku 0.00 0.00 –7.23 –0.07 0.00 2.28 –1.69 –0.50 0.00 –7.22 North 0.00 0.00 0.00 0.00 –2.28 0.00 –4.60 0.00 –0.15 –7.03 West – 14.46 0.00 –3.07 0.00 1.69 4.60 0.00 0.00 0.00 –11.24 Geographical sites: Vasavere 0.00 –0.48 0.00 1.07 0.50 0.00 0.00 0.00 0.00 1.09 Town of Jõhvi 0.00 0.00 0.00 0.00 0.00 0.15 0.00 0.00 0.00 0.15 Table 6. Water exchange between mines Mines, techno- genic water sub-bodies and geographical sites Water exchange, 106 m3 /y Comments Working mines: Aidu 14.46 Inflow from closed Kohtla mine Estonia 8.60 Main inflow from closed Ahtme mine, less from the direction of working Viru mine, partly also from the east Viru 8.83 Inflow from closed Tammiku and Sompa mines, slight outflow into Estonia mine Technogenic water body; closed mines (sub-bodies): Ahtme –7.65 Outflow mainly into Estonia mine and into the catchment area of the Pühajõgi River through springs and outflow wells Tammiku –7.22 Intensive water exchange with other parts of the water body, out flow into the catchment area of the Pühajõgi River through a caving at Kose Northern closed mines Käva, Kukruse and No. 2 –7.03 Feeds other closed mines, outflow via Vahtsepa ditch into the Kohtla River Western closed mines Kohtla, Sompa and Mine No 4. –11.24 Intensive water exchange with other parts of the water body, feeds mostly Aidu opencast Geographical sites: Vasavere 1.09 Water inflow mostly from Ahtme mine, to some extent also from closed Tammiku mine Town of Jõhvi 0.15 Water infiltrates from closed mine No. 2 Conclusions and recommendations No great changes in the water level of closed mines and its seasonal variation are expected if no measures are taken. The situation should not change after the closure of presently working mines either. In future the water level of flooded Aidu opencast will be regulated by an outlet into the Ojamaa River at 40–42 m level, which will be also the common water level in Kohtla and Sompa mines. In the area of Viru and Estonia mines the groundwater will rise to the pre-mining level, which will result in an increase in groundwater flow into the Pühajõgi River at the eastern margin of Tammiku and Ahtme mines. It may turn necessary to regulate water level in the mining district. In order to reduce the flow of groundwater from mine No. 2 to the lower, area of the town of Jõhvi, the following options could be considered: • outlet of water at 51 m level at the northern boundary of the mine, near the adit of unbuilt mine No. 1 Technogenic Water in Closed Oil Shale Mines 27 • blasting of the barrier between mine No. 2 and Käva and Tammiku mines to enable water outflow towards the Kohtla River (at a level of 51 m) or into the Pühajõgi River (at 45–47 m level) • building of a pumping station regulating the water level and operating seasonally, but this is evidently not efficient due to great expenses. In order to reduce the water amounts penetrating into working mines and towards Vasavere intake, it would be purposeful to lower the water level in several closed mines: • to 45 m level in Tammiku mine, by dredging the present outlet • to 42–43 m level in Ahtme mine, by drilling artesian wells The quality of the water of closed mines is improving. The content of sulphates and iron in mine water decreases and in about five years after the closure of the mine is below the maximum level permitted in drinking water. Monitoring the water quality in closed mines should be aimed mostly at protecting the water body from surface-derived pollution. The sampling methods should be improved, with indicating justified times and places for taking water samples. In some cases the number of parameters measured could be reduced. As no reliable data are available about the formation and distribution of phenols in the water of closed mines, corresponding investigations are needed before the use of the water. Although phenols are generally believed to originate from the waste of shale oil plants or from burning spoil dumps, the possibility of their formation during decomposition of kerogen in water- filled mines cannot be excluded either. This hypothesis deserves further special study. Acknowledgements This paper was written within the framework of Grant 5913 of the Estonian Science Foundation “Usage of mined-out areas”, using the database of research No. 416L “Forecast of hydrogeological changes resulting from the activities of the Estonian Oil Shale Mining Company” carried out by Tallinn University of Technology. REFERENCES 1. Reinsalu, E. Sillamäe uranium mine // Environment Technics. 2001. No. 2. P. 40–45 [in Estonian]. 2. Reinsalu, E. Changes in mine dewatering after the closure of exhausted oil shale mines // Oil Shale. 2005. Vol. 22, No. 3. P. 261–273. 3. Erg, K. Changes in groundwater sulphate content in Estonian oil shale mining area // Oil Shale. 2005. Vol. 22, No. 3. P. 275–289. 28 E. Reinsalu, I. Valgma, H. Lind, K. Sokman 4. Savitski, L., Savva, V. Prognosis of hydrogeological changes in the mining district of the Estonian oil shale deposit, stages 1–3, 2001 [in Estonian] 5. Reinsalu, E., Toomik, A., Valgma, I. 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